Abstract
Observations of transiting gas giant exoplanets have revealed a pervasive depletion of methane1,2,3,4, which has only recently been identified atmospherically5,6. The depletion is thought to be maintained by disequilibrium processes such as photochemistry or mixing from a hotter interior7,8,9. However, the interiors are largely unconstrained along with the vertical mixing strength and only upper limits on the CH4 depletion have been available. The warm Neptune WASP-107 b stands out among exoplanets with an unusually low density, reported low core mass10, and temperatures amenable to CH4 though previous observations have yet to find the molecule2,4. Here we present a JWST NIRSpec transmission spectrum of WASP-107 b which shows features from both SO2 and CH4 along with H2O, CO2, and CO. We detect methane with 4.2σ significance at an abundance of 1.0±0.5 ppm, which is depleted by 3 orders of magnitude relative to equilibrium expectations. Our results are highly constraining for the atmosphere and interior, which indicate the envelope has a super-solar metallicity of 43±8× solar, a hot interior with an intrinsic temperature of Tint=460±40 K, and vigorous vertical mixing which depletes CH4 with a diffusion coefficient of Kzz = 1011.6±0.1 cm2/s. Photochemistry has a negligible effect on the CH4 abundance, but is needed to account for the SO2. We infer a core mass of \({{\boldsymbol{11.5}}}_{-{\boldsymbol{3.6}}}^{+{\boldsymbol{3.0}}}\) M⊕, which is much higher than previous upper limits10, releasing a tension with core-accretion models11.
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Authors and Affiliations
Department of Earth & Planetary Sciences, Johns Hopkins University, Baltimore, MD, USA
David K. Sing&Zafar Rustamkulov
Department of Physics & Astronomy, Johns Hopkins University, Baltimore, MD, USA
David K. Sing,Daniel P. Thorngren&Elena Manjavacas
School of Physical Sciences, The Open University, Milton Keynes, UK
Joanna K. Barstow
Université Paris-Saclay, UVSQ, CNRS, CEA, Maison de la Simulation, Gif-sur-Yvette, France
Pascal Tremblin
Université Paris-Saclay, Université Paris Cité, CEA, CNRS, AIM, Gif-sur-Yvette, France
Pascal Tremblin
European Space Agency, European Space Astronomy Centre, 28692 Villanueva de la Canada, Madrid, Spain
Catarina Alves de Oliveira,Stephan M. Birkmann&Pierre Ferruit
Space Telescope Science Institute, Baltimore, MD, USA
Tracy L. Beck,Néstor Espinoza,Amélie Gressier&Jeff A. Valenti
Department of Astronomy and Carl Sagan Institute, Cornell University, Ithaca, NY, USA
Ryan C. Challener&Nikole K. Lewis
Leiden Observatory, Leiden University, P.O. Box 9513, Leiden, The Netherlands
Nicolas Crouzet
ATG Europe for the European Space Agency, ESTEC, Noordwijk, The Netherlands
Giovanna Giardino
Center for Space and Habitability, University of Bern, Bern, Switzerland
Elspeth K. H. Lee
University of Cambridge, The Old Schools, Trinity Ln, Cambridge, UK
Roberto Maiolino
AURA for the European Space Agency (ESA), ESA Office, Space Telescope Science Institute, Baltimore, MD, USA
Elena Manjavacas
NASA Goddard Space Flight Center, Greenbelt, MD, USA
Bernard J. Rauscher
European Space Agency (ESA), ESA Office, Space Telescope Science Institute, Baltimore, MD, USA
Marco Sirianni
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- David K. Sing
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- Zafar Rustamkulov
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- Daniel P. Thorngren
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- Joanna K. Barstow
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- Pascal Tremblin
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- Catarina Alves de Oliveira
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- Tracy L. Beck
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- Stephan M. Birkmann
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- Ryan C. Challener
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- Nicolas Crouzet
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- Néstor Espinoza
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- Pierre Ferruit
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- Giovanna Giardino
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- Amélie Gressier
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- Elspeth K. H. Lee
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- Nikole K. Lewis
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- Roberto Maiolino
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- Elena Manjavacas
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- Bernard J. Rauscher
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- Marco Sirianni
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- Jeff A. Valenti
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Correspondence to David K. Sing.
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Sing, D.K., Rustamkulov, Z., Thorngren, D.P. et al. A warm Neptune’s methane reveals core mass and vigorous atmospheric mixing. Nature (2024). https://doi.org/10.1038/s41586-024-07395-z
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DOI: https://doi.org/10.1038/s41586-024-07395-z
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